Covalent functionalization of black phosphorus nanoflakes by carbon free radicals for durable air and water stability

被引：88
|
作者：
Hu, Haiguo [1 ]
Gao, Hong [1 ]
Gao, Lili [1 ]
Li, Feng [1 ]
Xu, Na [1 ]
Long, Xuefeng [1 ]
Hu, Yiping [1 ]
Jin, Jun [1 ]
Ma, Jiantai [1 ]
机构：
[1] Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Catalyt Engn Gansu Prov & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
NANOSCALE | 2018年 / 10卷 / 13期
基金：
美国国家科学基金会;
关键词：
BAND-GAP; GRAPHENE; PERFORMANCE; EFFICIENT; PHOTOCATALYST; DEGRADATION; PASSIVATION; TRANSISTORS; EXFOLIATION; COMPOSITE;
D O I：
10.1039/c7nr06085h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This work developed a simple and efficient method to covalently functionalize black phosphorus nanoflakes (BPNFs) with carbon free radicals from azodiisobutyronitrile (AIBN) molecules. BPNFs after successful modification (BPNFs-AIBN) not only had good stability in air and aqueous solution, but also still maintained good optical properties.
引用
收藏
页码：5834 / 5839
页数：6
相关论文
共 50 条
  • [31] Black phosphorus nanoflakes decorated hematite photoanode with functional phosphate bridges for enhanced water oxidation
    Shao, Shan
    Deng, Jiujun
    Lv, Xiaoxin
    Ji, Haiyan
    Xiao, Ying
    Zhu, Xingwang
    Feng, Kun
    Xu, Hui
    Zhong, Jun
    CHEMICAL ENGINEERING JOURNAL, 2021, 425
  • [32] Noncovalent and covalent functionalization of a (5, 0) single-walled carbon nanotube with alanine and alanine radicals
    Muthusivarajan Rajarajeswari
    Kombiah Iyakutti
    Yoshiyuki Kawazoe
    Journal of Molecular Modeling, 2012, 18 : 771 - 781
  • [33] NiFeP nanoflakes composite with CoP on carbon cloth as flexible and durable electrocatalyst for efficient overall water splitting
    Li, Mai
    Li, Sa
    Wang, Jiale
    Wang, Chunrui
    Li, Wan
    Chu, Paul K.
    NANOTECHNOLOGY, 2019, 30 (48)
  • [34] Quasi-Monolayer Black Phosphorus with High Mobility and Air Stability
    Tan, Sherman Jun Rong
    Abdelwahab, Ibrahim
    Chu, Leiqiang
    Poh, Sock Mui
    Liu, Yanpeng
    Lu, Jiong
    Chen, Wei
    Loh, Kian Ping
    ADVANCED MATERIALS, 2018, 30 (06)
  • [35] One-Pot Covalent Functionalization of 2D Black Phosphorus by Anionic Ring Opening Polymerization
    Bawadkji, Obida
    Cherri, Mariam
    Schaefer, Andreas
    Herziger, Svenja
    Nickl, Philip
    Achazi, Katharina
    Donskyi, Ievgen S.
    Adeli, Mohsen
    Haag, Rainer
    ADVANCED MATERIALS INTERFACES, 2022, 9 (32):
  • [36] Black phosphorus nanoflakes as morphology modifier for efficient fullerene-free organic solar cells with high fill-factor and better morphological stability
    Yang, Weitao
    Ye, Long
    Yao, Fenfa
    Jin, Chuanhong
    Ade, Harald
    Chen, Hongzheng
    NANO RESEARCH, 2019, 12 (04) : 777 - 783
  • [37] Black phosphorus nanoflakes as morphology modifier for efficient fullerene-free organic solar cells with high fill-factor and better morphological stability
    Weitao Yang
    Long Ye
    Fenfa Yao
    Chuanhong Jin
    Harald Ade
    Hongzheng Chen
    Nano Research, 2019, 12 : 777 - 783
  • [38] In Situ Visualization on Surface Oxidative Corrosion with Free Radicals: Black Phosphorus Nanoflake as an Example
    Li, Meirong
    Mao, Chengliang
    Ling, Lan
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2022, 56 (01) : 361 - 367
  • [39] Noncovalent and covalent functionalization of a (5,0) single-walled carbon nanotube with alanine and alanine radicals
    Rajarajeswari, Muthusivarajan
    Iyakutti, Kombiah
    Kawazoe, Yoshiyuki
    JOURNAL OF MOLECULAR MODELING, 2012, 18 (02) : 771 - 781
  • [40] Passivation of black phosphorus nanoflakes embedded in a silica glass matrix affords ambient saturable absorption stability enhancement
    Ma, Xueting
    Liu, Jialiang
    Zheng, Chan
    Huang, Li
    Li, Wei
    Cai, Shuguang
    Xiao, Xueqing
    APPLIED OPTICS, 2022, 61 (15) : 4638 - 4647
12345