Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials

被引：51
|
作者：
Park, Sanghyuk [1 ]
Kim, Sehoon [1 ]
Seo, Jangwon [1 ]
Park, Soo Young [1 ]
机构：
[1] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul 151744, South Korea
来源：
MACROMOLECULAR RESEARCH | 2008年 / 16卷 / 05期
关键词：
fluorescence; excited-state intramolecular proton transfer; optical patterning; electroluminescence; amplified spontaneous emission;
D O I：
10.1007/BF03218534
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Synthesis and properties of novel excited-state intramolecular proton transfer (ESIPT) materials, recently developed in our group, are described. Highly efficient ESIPT reaction, achieved in polyquinolines, polybenzoxazoles, and oxadiazole and imidazole derivatives possessing an intramolecular tautomerizable hydrogen bond, has been investigated theoretically and experimentally. It is demonstrated that unique properties arising from the ESIPT process (large Stokes' shift, no self-absorption, and easy population inversion, etc.) make it possible to produce advanced polymer devices for lasing, optical storage, and electroluminescence.
引用
收藏
页码：385 / 395
页数：11
相关论文
共 50 条
  • [41] On estimating probability of excited-state intramolecular proton transfer
    Tomin, V. I.
    OPTICS AND SPECTROSCOPY, 2010, 108 (05) : 714 - 719
  • [42] Ratiometric sensing of β-galactosidase based on excited-state intramolecular proton transfer (ESIPT) and solid-state luminescence enhancement
    Tian Jr, He
    Lin, Wei
    Hu, Xi-Le
    Wang, Jing-Bo
    Zhang, Min-Yu
    Zang, Yi
    Wu, Xin-Yan
    Li, Jia
    James, Tony D.
    He, Xiao-Peng
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (12) : 2913 - 2917
  • [43] Imidazole-based excited-state intramolecular proton-transfer(ESIPT) materials: Observation of thermally activated delayed fluorescence(TDF)
    Park, Sanghyuk
    Kwon, Oh-Hoon
    Lee, Young-Shin
    Jang, Du-Jeon
    Park, Soo Young
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (39): : 9649 - 9653
  • [44] Tailoring the excited-state intramolecular proton transfer (ESIPT) fluorescence of 2-(2′-hydroxyphenyl)benzoxazole derivatives
    Seo, J
    Kim, S
    Park, S
    Park, SY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (11) : 1706 - 1710
  • [45] Excited-state intramolecular proton transfer (ESIPT)-type phosphorescence of 2-aminobenzophenone in 77 K matrices
    Hagiri, M
    Ichinose, N
    Kinugasa, J
    Iwasa, T
    Nakayama, T
    CHEMISTRY LETTERS, 2004, 33 (03) : 326 - 327
  • [46] Singlet Fission Driven by Excited-State Intramolecular Proton Transfer (ESIPT+SF): A (TD)DFT Study
    Lopez-Carballeira, Diego
    Polcar, Tomas
    CHEMPHOTOCHEM, 2023, 7 (07)
  • [47] Theoretical insights into excited-state hydrogen bonding effects and intramolecular proton transfer (ESIPT) mechanism for BTS system
    Wang, Jiemin
    Liu, Qiang
    Yang, Dapeng
    SCIENTIFIC REPORTS, 2020, 10 (01)
  • [48] Recent Advances in Smart Sensing Based on Excited-State Intramolecular Proton-Transfer (ESIPT)-Inspired Emitters
    Li, Jing
    Xu, Bao-Sen
    Zhao, Le-Le
    Yi, Shao-Zhe
    Li, Bao-Ning
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2025, 14 (02)
  • [49] Excited-State Intramolecular Proton Transfer (ESIPT) of Fluorescent Flavonoid Dyes: A Close Look by Low Temperature Fluorescence
    Bi, Xiaoman
    Liu, Bin
    McDonald, Lucas
    Pang, Yi
    JOURNAL OF PHYSICAL CHEMISTRY B, 2017, 121 (19): : 4981 - 4986
  • [50] Curcumin. in Reverse Micelle: An Example to Control Excited-State Intramolecular Proton Transfer (ESIPT) in Confined Media
    Banerjee, Chiranjib
    Ghatak, Chiranjib
    Mandal, Sarthak
    Ghosh, Surajit
    Kuchlyan, Jagannath
    Sarkar, Nilmoni
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (23): : 6906 - 6916
12345