Synthesis and characterization of 1D iron(II) spin crossover coordination polymers with hysteresis

被引：27

作者：

Bauer, Wolfgang ^{[1
]}

Lochenie, Charles ^{[1
]}

Weber, Birgit ^{[1
]}

机构：

[1] Univ Bayreuth, D-95440 Bayreuth, Germany

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 05期

关键词：

WIDE THERMAL HYSTERESIS; MAGNETIC-PROPERTIES; MOLECULAR MATERIALS; TRANSITION; COMPLEX;

D O I：

10.1039/c3dt52635f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Purposeful ligand design was used for the synthesis of eight new 1D iron(II) spin crossover coordination polymers aiming for cooperative spin transitions with hysteresis. The results from magnetic measurements and X-ray structure analysis show that the combination of rigid linkers and a hydrogen bond network between the 1D chains is a promising tool to reach this goal. Five of the eight new samples show a cooperative spin transition with hysteresis with up to 43 K wide hysteresis loops.

引用

页码：1990 / 1999

页数：10

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