Synthesis and photoconductivity study of phthalocyanine polymers .5. 4,4'-diamino-Diphenyl ether bridged polymeric SiPc

被引:0
|
作者
Chen, HZ
Wang, M
Yang, SL
机构
[1] Dept. of Poly. Sci. and Engineering, Zhejiang University
关键词
photoconductivity; bridged polymeric phthalocyanine; one-dimensional structure;
D O I
10.1002/(SICI)1099-0518(19970115)35:1<91::AID-POLA10>3.0.CO;2-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel polymer with quasi-one-dimensional structure of 4,4'-diamino-diphenyl ether bridged polymeric silicon phthalocyanine (I) is synthesized by the condensation polymerization of 4,4'-diamino-diphenyl ether (DDE) monomer and dichloride silicon phthalocyanine (Cl(2)SiPc) monomer. The structure of the polymer (I) is identified by IR subtraction and UV/VIS spectroscopy and elemental analysis. The photoconductivity of the polymer I with quasi-one-dimensional structure is better than that of not only the parent Cl(2)SiPc reactant, but also other polymeric phthalocyanines without one-dimensional structures, and showing one-dimensional effect of molecular structure. (C) 1997 John Wiley & Sons, Inc.
引用
收藏
页码:91 / 95
页数:5
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