Single-crystal to single-crystal transformations in discrete solvated metallocycles: the role of the metal ion

被引：12
|
作者：
Jacobs, Tia [1 ]
Barbour, Leonard J. [1 ]
机构：
[1] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7602 Matieland, South Africa
来源：
NEW JOURNAL OF CHEMISTRY | 2013年 / 37卷 / 01期
关键词：
ORGANIC FRAMEWORKS; GUEST REMOVAL; MOLECULES; POROSITY; COMPLEX; SYSTEMS;
D O I：
10.1039/c2nj40612h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystals of solvated cobalt- and zinc-containing metallocycles undergo single-crystal to single-crystal (SCTSCT) transformations upon desolvation to yield their close-packed forms; this is in stark contrast to the analogous cadmium-based metallocycle, which affords an empty, transiently porous phase upon desolvation.
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页码：71 / 74
页数：4
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