Nonlinear optical properties of chiral thiolates

被引：9
|
作者：
Sylla, M
Giffard, M
Boucher, V
Illien, B
Mercier, N
Phu, XN
机构：
[1] Univ Angers, Lab Proprietes Opt Mat & Applicat, F-49045 Angers, France
[2] Univ Angers, Lab Ingn Mol & Mat Organ, F-49045 Angers, France
[3] Univ Nantes, Lab Spectrochim, F-44322 Nantes, France
来源：
SYNTHETIC METALS | 1999年 / 102卷 / 1-3期
关键词：
semi-empirical models; nonlinear optical models and methods; coupling reactions;
D O I：
10.1016/S0379-6779(98)00548-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Aromatic thiolate anions ArS- are expected from a semi-empirical calculation with PM3 parametrisation of the MNDO Hamiltonian, to possess higher intrinsic polarizabilities than the parent neutral thiols ArSH Noncentrosymmetric thiolate salts have been synthesized by the reaction of ArSH with chiral amines and investigated for their second-order(through frequency doubling) and third-order (through degenerate four-wave mixing technique) nonlinear optical properties.
引用
收藏
页码：1548 / 1549
页数：2
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