g-C3N4/NaTaO3 organic-inorganic hybrid nanocomposite: High-performance and recyclable visible light driven photocatalyst

被引:50
|
作者
Kumar, Santosh [1 ]
Kumar, Bharat [2 ]
Surendar, T. [1 ]
Shanker, Vishnu [1 ]
机构
[1] Natl Inst Technol, Dept Chem, Warangal 506004, Andhra Pradesh, India
[2] Indian Inst Technol, Dept Chem, New Delhi 110016, India
关键词
Composites; Nanostructures; Semiconductors; Chemical synthesis; Catalytic properties; LANTHANUM-DOPED NATAO3; HYDROTHERMAL SYNTHESIS; TANTALATE PHOTOCATALYSTS; WATER; EFFICIENT; H-2; NA; NANOPARTICLES; NANORODS; ATAO(3);
D O I
10.1016/j.materresbull.2013.09.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Novel g-C3N4/NaTaO3 hybrid nanocomposites have been prepared by a facile ultrasonic dispersion method. Our results clearly show the formation of interface between NaTaO3 and g-C3N4 and further loading of g-C3N4 did not affect the crystal structure and morphology of NaTaO3. The g-C3N4/NaTaO3 nanocomposites exhibited enhanced photocatalytic performance for the degradation of Rhodamine B under UV visible and visible light irradiation compared to pure NaTaO3 and Degussa P25. Interestingly, the visible light photocatalytic activity is generated due to the loading of g-C3N4. A mechanism is proposed to discuss the enhanced photocatalytic activity based on trapping experiments of photoinduced radicals and holes. Under visible light irradiation, electron excited from the valance band (VB) to conduction band (CB) of g-C3N4 could directly inject into the CB of NaTaO3, making g-C3N4/NaTaO3 visible light driven photocatalyst. Since the as-prepared hybrid nanocomposites possess high reusability therefore it can be promising photocatalyst for environmental applications. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:310 / 318
页数:9
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