Cucurbit[8]uril-based supramolecular polymers: promoting supramolecular polymerization by metal-coordination

被引：104
|
作者：
Liu, Yiliu [1 ]
Huang, Zehuan [1 ]
Tan, Xinxin [1 ]
Wang, Zhiqiang [1 ]
Zhang, Xi [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 51期
关键词：
CHARGE-TRANSFER INTERACTIONS; ORTHOGONAL BINDING INTERACTIONS; PI-PI INTERACTION; SMALL-MOLECULE; WATER; CUCURBITURIL; CHEMISTRY; MONOMERS;
D O I：
10.1039/c3cc41864b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Linear supramolecular polymers were obtained in aqueous solution by employing cucurbit[8]uril-based host-guest interaction as the driving force. Water-soluble monomers were prepared through direct metal-coordination. The rigid and bulky terpyridine-Fe linker can effectively enhance the monomer's solubility and suppress its cyclization, thereby promoting supramolecular polymerization.
引用
收藏
页码：5766 / 5768
页数：3
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