Crystal Structure Of a 2D Cadmium(II) Coordination Polymer Containing a Flexible bis(imidazole) Ligand

被引：2
|
作者：
Cheng, J. [1 ]
Wang, G. -H. [1 ]
Wang, Y. -W. [1 ]
机构：
[1] Environm Management Coll China, Journal Editorial Dept, Qinhuangdao, Hebei, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 01期
关键词：
bis(imidazole); cadmium complex; crystal structure; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENT PROPERTIES; LUMINESCENT PROPERTIES; COMPLEXES; CONSTRUCTION; DIVERSITY; CLUSTERS; ZINC(II); DESIGN; ACID;
D O I：
10.1134/S0022476618010353
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer {[Cd(mbix)(nip)center dot H2O]center dot 0.25H(2)O}n (mbix = 1,3-bis(imidazol-1-ylmethyl)benzene, H(2)nip = 5-nitroisophthalic acid) is hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2(1)/c, a = 10.328(1) , b = 26.683(3) , c = 8.6612(8) , beta = 107.462(1)A degrees, V = 2276.9(4) (3), Z = 4, D (c) = 1.699 g/cm(3), mu = 1.015 mm(-1), F(000) = 1170, the final R = 0.0469 and wR = 0.0833. The complex exhibits a 2D (4,4) grid with point symbol 4(4).6(2). The thermogravimetric curve of the complex was addressed.
引用
收藏
页码：222 / 226
页数：5
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