Regioselective Hydrogenation of 1,2-Indanedione Over Heterogeneous Pd and Pt Catalysts

被引：5
|
作者：
Langvik, Otto [1 ]
Maki-Arvela, Paivi [2 ]
Aho, Atte [2 ]
Saloranta, Tiina [1 ]
Murzin, Dmitry Yu [2 ]
Leino, Reko [1 ]
机构：
[1] Abo Akad Univ, Organ Chem Lab, SF-20500 Turku, Finland
[2] Abo Akad Univ, Proc Chem Ctr, Lab Ind Chem & React Engn, SF-20500 Turku, Finland
来源：
CATALYSIS LETTERS | 2013年 / 143卷 / 02期
关键词：
1,2-Indanedione; 2-Hydroxy-1-indanone; Regioselectivity; Heterogeneous catalysis; Hydrogenation; DYNAMIC KINETIC RESOLUTION; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE HYDROGENATION; PALLADIUM; ALUMINA; CIS-1-AMINO-2-INDANOL; DEACTIVATION; REGENERATION; CINCHONIDINE; DEPOSITION;
D O I：
10.1007/s10562-012-0951-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.
引用
收藏
页码：142 / 149
页数：8
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