Regioselective Hydrogenation of 1,2-Indanedione Over Heterogeneous Pd and Pt Catalysts

被引：5

作者：

Langvik, Otto ^{[1
]}

Maki-Arvela, Paivi ^{[2
]}

Aho, Atte ^{[2
]}

Saloranta, Tiina ^{[1
]}

Murzin, Dmitry Yu ^{[2
]}

Leino, Reko ^{[1
]}

机构：

[1] Abo Akad Univ, Organ Chem Lab, SF-20500 Turku, Finland

[2] Abo Akad Univ, Proc Chem Ctr, Lab Ind Chem & React Engn, SF-20500 Turku, Finland

来源：

CATALYSIS LETTERS | 2013年 / 143卷 / 02期

关键词：

1,2-Indanedione; 2-Hydroxy-1-indanone; Regioselectivity; Heterogeneous catalysis; Hydrogenation; DYNAMIC KINETIC RESOLUTION; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE HYDROGENATION; PALLADIUM; ALUMINA; CIS-1-AMINO-2-INDANOL; DEACTIVATION; REGENERATION; CINCHONIDINE; DEPOSITION;

D O I：

10.1007/s10562-012-0951-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Regioselective hydrogenation of 1,2-indanedione yielding rac-2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al2O3. Practical operation under atmospheric pressure of hydrogen at low temperature (40 A degrees C) for 120 min gave the desired product in > 99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al2O3 as the catalyst.

引用

页码：142 / 149

页数：8

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