Synthesis of Dimethyl Glutarate from Cyclobutanone and Dimethyl Carbonate over Solid Base Catalysts

被引：0
|
作者：
Chen Zhi [1 ]
Wu Dudu [2 ]
机构：
[1] Guangdong Med Coll, Ctr Anal, Dongguan 523808, Peoples R China
[2] Guangdong Med Coll, Sch Pharm, Dongguan 523808, Peoples R China
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 06期
关键词：
Dimethyl glutarate; Cyclobutanone; Dimethyl carbonate; Solid base catalysts; METHYLATION; ANILINE; KETONES; PHENOL;
D O I：
10.5012/bkcs.2012.33.6.1834
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile route for the synthesis of dimethyl glutarate (DMG) from cyclobutanone and dimethyl carbonate (DMC) in the presence of solid base catalysts has been developed. It was found that the intermediate carbomethoxycyclobutanone (CMCB) was produced from cyclobutanone with DMC in the first step, and then CMCB was further converted to DMG by reacting with a methoxide group. The role of the basic catalysts can be mainly ascribed to the activation of cyclobutanone via the abstraction of a proton in the alpha-position by base sites, and solid bases with moderate strength, such as MgO, favor the formation of DMG.
引用
下载
收藏
页码：1834 / 1838
页数：5
相关论文
共 50 条
  • [1] Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts
    WU DuDu CHEN Zhi JIA ZhenBin SHUAI Li School of PharmacyGuangdong Medical CollegeDongguan China School of PharmacySouth Central University for NationalitiesWuhan China
    Science China(Chemistry), 2012, 55 (03) : 380 - 385
  • [2] Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts
    Wu DuDu
    Chen Zhi
    Jia ZhenBin
    Shuai Li
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (03) : 380 - 385
  • [3] Synthesis of dimethyl pimelate from cyclohexanone and dimethyl carbonate over solid base catalysts
    Wu, Dudu
    Zhao, Ning
    Li, Junping
    Xiao, Fukui
    Wei, Wei
    Sun, Yuhan
    Shiyou Huagong/Petrochemical Technology, 2007, 36 (08): : 812 - 815
  • [4] Synthesis of Dimethyl Pimelate from Cyclohexanone and Dimethyl Carbonate over Solid Base Catalysts
    Wu, Dudu
    Chen, Zhi
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (13) : 6287 - 6290
  • [5] Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts
    WU DuDu 1
    Science China Chemistry, 2012, (03) : 380 - 385
  • [6] Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts
    DuDu Wu
    Zhi Chen
    ZhenBin Jia
    Li Shuai
    Science China Chemistry, 2012, 55 : 380 - 385
  • [7] Synthesis of dimethyl carbonate from urea and methanol over solid base catalysts
    Wang, MH
    Wang, H
    Zhao, N
    Wei, W
    Sun, YH
    CATALYSIS COMMUNICATIONS, 2006, 7 (01) : 6 - 10
  • [8] Synthesis of MDI from dimethyl carbonate over solid catalysts
    Zhao, XQ
    Wang, YJ
    Wang, SF
    Yang, HJ
    Zhang, JY
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (21) : 5139 - 5144
  • [9] Synthesis of dimethyl carbonate by transesterification over CaO/carbon solid base catalysts
    Wei, T
    Wang, MH
    Wei, W
    Sun, YH
    Zhong, B
    CARBON DIOXIDE UTILIZATION FOR GLOBAL SUSTAINABILITY, 2004, 153 : 41 - 46
  • [10] Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts
    Wu, Dudu
    Chang, Wenming
    Wen, Xia
    Xiao, Fukui
    Li, Junping
    Zhao, Ning
    Wei, Wei
    Sun, Yuhan
    FUEL PROCESSING TECHNOLOGY, 2008, 89 (08) : 803 - 807
12345