Thermal expansion of β-eucryptite in oxide-based ceramic composites

被引:17
|
作者
Pelletant, A. [1 ,2 ]
Reveron, H. [1 ,2 ]
Chevalier, J. [1 ,2 ]
Fantozzi, G. [1 ,2 ]
Guinot, F. [3 ]
Blanchard, L. [3 ]
Falzon, F. [3 ]
机构
[1] Inst Natl Sci Appl, MATEIS UMR5510, F-69621 Villeurbanne, France
[2] Univ Lyon, CNRS, Lyon, France
[3] Thales Alenia Space, F-06156 Cannes La Bocca, France
关键词
Composites; Thermal expansion; Mechanical properties; Al2O3; beta-Eucryptite; HIGH-STRENGTH; X-RAY; TRANSFORMATION; MICROSTRUCTURE; COEFFICIENT; POWDER; SYSTEM;
D O I
10.1016/j.jeurceramsoc.2012.09.022
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper presents an experimental investigation on the thermal expansion behaviour of beta-eucryptite (E) when it is used for processing alumina/beta-eucryptite (AE) or zirconia/beta-eucryptite (ZE) composites. Composite materials were prepared from a beta-eucryptite powder synthetised in our laboratory and commercially available alumina or zirconia nanopowders. In order to preserve the beta-eucryptite crystalline phase in sintered materials, the pressureless sintered step was performed at relatively low temperatures (<1300 degrees C). It is experimentally shown that in well-densified oxide-based composites, the beta-eucryptite lost its slightly negative thermal expansion coefficient. This behaviour could be related to compressive residual stresses applied on beta-eucryptite grains due to the thermal expansion mismatch between alumina or zirconia and the beta-eucryptite. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:531 / 538
页数:8
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