2,2′:6′,2"-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(II) complexes

被引：108

作者：

Schulze, Benjamin ^{[1
,2
]}

Friebe, Christian ^{[1
,2
]}

Hager, Martin D. ^{[2
]}

Winter, Andreas ^{[2
]}

Hoogenboom, Richard ^{[2
]}

Goerls, Helmar ^{[3
]}

Schubert, Ulrich S. ^{[1
,2
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

[2] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[3] Univ Jena, Inorgan & Analyt Chem Lab, D-07743 Jena, Germany

来源：

DALTON TRANSACTIONS | 2009年 / 05期

关键词：

CLICK CHEMISTRY; SPECTROSCOPIC PROPERTIES; EFFICIENT SYNTHESIS; POLYMERS; AZIDES; CYCLOADDITION; ROTAXANES; DONOR;

D O I：

10.1039/b813925c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a series of heteroleptic ruthenium(II)-complexes containing both, 2,2':6',2 ''-terpyridine and 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine, is reported for the first time. The provided complexes feature photophysical and electrochemical properties in between those known for the respective homoleptic complexes. The flexibility with respect to lateral functional groups to be introduced into the complexes underlines the high potential for further functionalization steps.

引用

页码：787 / 794

页数：8

共 50 条

[41] [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
Ren, Chun-Xia
Li, Su-Yun
Yin, Zhao-Zhong
Lu, Xiang
Ding, Yu-Qiang
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M572 - U976
[42] Novel complexes of 2,6-bis(benzthiazol-2-yl)pyridine
Boca, M
Boca, R
Kickelbick, G
Linert, W
Svoboda, I
Fuess, H
INORGANICA CHIMICA ACTA, 2002, 338 : 36 - 50
[43] Synthesis of [5-(1H-1,2,3-triazol-4-yl)-1,3,4-oxadiazol-2-yl]pyridines
Pokhodylo, N. T.
Shiika, O. Ya.
Matiichuk, V. S.
Obushak, N. D.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (03) : 417 - 421
[44] ZnII and PbII coordination chemistry of 2,6-bis(1,2,3-triazol-4-yl)pyridine (clickate) and the metal ion-dependent emission of 'clickate'-appended anthracene
Younes, Ali H.
Clark, Ronald J.
Zhu, Lei
SUPRAMOLECULAR CHEMISTRY, 2012, 24 (09) : 696 - 706
[45] Bis(2,2 ':6 ',2 ''-terpyridine) ruthenium(II) bis(perchlorate) hemihydrate
Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Breczko, Joanna
Brzezinski, Krzysztof
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1414 - +
[46] A pyrazolyl-terminated 2,2′:6′,2"-terpyridine ligand:: Iron(II), ruthenium(II) and palladium(II) complexes of 4′-(3,5-dimethylpyrazol-1-yl)-2,2′:6′,2"-terpyridine
Beves, Jonathon E.
Constable, Edwin C.
Housecroft, Catherine E.
Neuburger, Markus
Schaffner, Silvia
POLYHEDRON, 2008, 27 (11) : 2395 - 2401
[47] Synthesis of [5-(1H-1,2,3-triazol-4-yl)-1,3,4-oxadiazol-2-yl]pyridines
N. T. Pokhodylo
O. Ya. Shiika
V. S. Matiichuk
N. D. Obushak
Russian Journal of Organic Chemistry, 2010, 46 : 417 - 421
[48] Back to back 2,6-bis(pyrazol-1-yl)pyridine and 2,2′:6′,2"-terpyridine ligands: Untapped potential for spin crossover research and beyond
Attwood, Max
Turner, Scott S.
COORDINATION CHEMISTRY REVIEWS, 2017, 353 : 247 - 277
[49] Photophysical properties of closely-coupled, binuclear ruthenium(II) bis(2,2′:6′,2"-terpyridine)complexes
Benniston, AC
Grosshenny, V
Harriman, A
Ziessel, R
DALTON TRANSACTIONS, 2004, (08) : 1227 - 1232
[50] Phosphonate-functionalized heteroleptic ruthenium(II) bis(2,2′:6′,2"-terpyridine) complexes
Constable, Edwin C.
Housecroft, Catherine E.
Smidkova, Marketa
Zampese, Jennifer A.
CANADIAN JOURNAL OF CHEMISTRY, 2014, 92 (08) : 724 - 730

← 1 2 3 4 5 →