Comments on "Solubility and thermodynamic properties of 5-nitrofurazone form γ in mono-solvents and binary solvent mixtures"

被引：1
|
作者：
Acree, William E., Jr. [1 ]
机构：
[1] Univ North Texas, Dept Chem, Denton, TX 76203 USA
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 277卷
关键词：
Thermodynamic mixing properties; Thermodynamic dissolution properties; Solubility; Thermodynamic consistency;
D O I：
10.1016/j.molliq.2018.12.086
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A polemic is given concerning the thermodynamic dissolution properties in the published paper by Li and co-workers IJ. Mol. Liq. 275 (2019) 815-8281 The published numerical values do not obey the standard thermodynamic relationship given by Delta(diss)G = Delta H-diss - T Delta S-diss, where Delta(diss)G, Delta H-diss and Delta S-diss refer to the Gibbs energy, enthalpy and entropy of dissolution. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：78 / 79
页数：2
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