Highly Atom-Efficient Oxidation of Electron-Deficient Internal Olefins to Ketones Using a Palladium Catalyst

被引：39

作者：

Mitsudome, Takato ^{[1
]}

Yoshida, Syuhei ^{[1
]}

Mizugaki, Tomoo ^{[1
]}

Jitsukawa, Koichiro ^{[1
]}

Kaneda, Kiyotomi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Osaka Univ, Res Ctr Solar Energy Chem, Toyonaka, Osaka 5608531, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 23期

关键词：

ketones; molecular oxygen; olefins; oxidation; palladium; REGIOSELECTIVE OXIDATION; MOLECULAR-OXYGEN; WACKER REACTION; REOXIDANT; SYSTEM;

D O I：

10.1002/anie.201301611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 100 % atom-efficient synthesis of ketones from electron-deficient internal olefins was achieved using O2 as a "green" oxidant (see scheme, DMA=N,N-dimethylacetamide, EWG=electron-withdrawing group). Various electron-deficient olefins were oxidized to the corresponding ketones with over 99 % selectivity and without the formation of olefin isomers or their oxidized products. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5961 / 5964

页数：4

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