Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles

被引：203

作者：

Parr, Brendan T. ^{[1
]}

Green, Samantha A. ^{[1
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 12期

基金：

美国国家科学基金会;

关键词：

TRANSANNULATION; REACTIVITY; CARBENES; COPPER;

D O I：

10.1021/ja401386z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of highly functionalized pyrroles has been achieved by reaction of rhodium-stabilized imino-carbenes with furans. The reaction features an initial [3+2] annulation to form bicyclic hemiaminals, followed by ring opening to generate trisubstituted pyrroles.

引用

页码：4716 / 4718

页数：3

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