Experimental Study of Methane Hydrate Decomposition Kinetics

被引：13
|
作者：
Windmeier, Christoph [1 ]
Oellrich, Lothar R. [2 ]
机构：
[1] Linde AG, Div Engn, D-82049 Pullach, Germany
[2] Karlsruher Inst Technol, Inst Tech Thermodynam & Kaltetech, D-76128 Karlsruhe, Germany
来源：
CHEMIE INGENIEUR TECHNIK | 2015年 / 87卷 / 07期
关键词：
Clathrate; Crystallization; Decomposition; Kinetics; Multiphase reactions; Phase change; MASS-TRANSFER; EQUATION; STATE;
D O I：
10.1002/cite.201400122
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Experimental investigations of methane hydrate dissociation kinetics were performed. The test rig consists of a stirred reactor equipped with particle size analysis. The observed dissociation rates were found to be about one order of magnitude faster than previously reported by others. A mass transfer control of the dissociation process is proposed to dominate in the proximity of a dispersed hydrate-liquid interface. The results are relevant for the design of processes employing dispersed gas hydrates in chemical engineering and the production of natural gas from dispersed deposits.
引用
下载
收藏
页码：910 / 921
页数：12
相关论文
共 50 条
  • [31] Experimental Investigation on Cyclopentane-Methane Hydrate Formation Kinetics in Brine
    Zang, Xueru
    Lv, Qiunan
    Li, Xiaosen
    Li, Gang
    ENERGY & FUELS, 2017, 31 (01) : 824 - 830
  • [32] Experimental study on sediment deformation during methane hydrate decomposition in sandy and silty clay sediments with a novel experimental apparatus
    Han, Han
    Wang, Yi
    Li, Xiao-Sen
    Yu, Jian-Xing
    Feng, Jing-Chun
    Zhang, Yu
    FUEL, 2016, 182 : 446 - 453
  • [33] Experimental study of methane hydrate formation and decomposition in the porous medium with different thermal conductivities and grain sizes
    Li, Xiao-Yan
    Feng, Jing-Chun
    Li, Xiao-Sen
    Wang, Yi
    Hu, Heng-Qi
    APPLIED ENERGY, 2022, 305
  • [34] Formation and decomposition of methane hydrate in coal
    Smirnov, Vyacheslav G.
    Manakov, Andrey Yu.
    Ukraintseva, Elissa A.
    Villevald, Galina V.
    Karpova, Tamara D.
    Dyrdin, Valeriy V.
    Lyrshchikov, Sergey Yu.
    Ismagilov, Zinfer R.
    Terekhova, Irina S.
    Ogienko, Andrey G.
    FUEL, 2016, 166 : 188 - 195
  • [35] Experimental study on the intrinsic dissociation rate of methane hydrate
    Wang, Xiao-Hui
    Xu, Xiao-Jie
    Cai, Jin
    Wu, Yi-Wei
    Chen, Yi-Xin
    Pang, Wei-Xin
    Sun, Chang-Yu
    Chen, Guang-Jin
    CHEMICAL ENGINEERING SCIENCE, 2023, 282
  • [36] Study on the kinetics of methane hydrate formation in the carbon microtube system
    Lv, Xiaofang
    Jing, Shu
    Gao, Qiuying
    Ye, Fan
    Liu, Yang
    Ma, Qianli
    Song, Shangfei
    Zhou, Shidong
    JOURNAL OF CRYSTAL GROWTH, 2022, 593
  • [37] Methane hydrate studies: Delineating properties of host sediments to establish reproducible decomposition kinetics
    Mahajan, D
    Servio, P
    Jones, KW
    Feng, H
    Winters, WJ
    ADVANCES IN THE STUDY OF GAS HYDRATES, 2004, : 239 - 250
  • [38] Methane hydrate film growth kinetics
    Freer, EM
    Selim, MS
    Sloan, ED
    FLUID PHASE EQUILIBRIA, 2001, 185 (1-2) : 65 - 75
  • [39] Theoretical Study of Gas Hydrate Decomposition Kinetics: Model Predictions
    Windmeier, Christoph
    Oellrich, Lothar R.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (47): : 12184 - 12195
  • [40] In-situ Raman and kinetic study on the methane hydrate formation and decomposition
    Cho, Seong Jun
    Hai, Truong Lam Son
    Lee, Ju Dong
    INNOVATIVE SOLUTIONS FOR ENERGY TRANSITIONS, 2019, 158 : 5615 - 5621
12345