Experimental Study of Methane Hydrate Decomposition Kinetics

被引:13
|
作者
Windmeier, Christoph [1 ]
Oellrich, Lothar R. [2 ]
机构
[1] Linde AG, Div Engn, D-82049 Pullach, Germany
[2] Karlsruher Inst Technol, Inst Tech Thermodynam & Kaltetech, D-76128 Karlsruhe, Germany
关键词
Clathrate; Crystallization; Decomposition; Kinetics; Multiphase reactions; Phase change; MASS-TRANSFER; EQUATION; STATE;
D O I
10.1002/cite.201400122
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Experimental investigations of methane hydrate dissociation kinetics were performed. The test rig consists of a stirred reactor equipped with particle size analysis. The observed dissociation rates were found to be about one order of magnitude faster than previously reported by others. A mass transfer control of the dissociation process is proposed to dominate in the proximity of a dispersed hydrate-liquid interface. The results are relevant for the design of processes employing dispersed gas hydrates in chemical engineering and the production of natural gas from dispersed deposits.
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页码:910 / 921
页数:12
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