Oxidation of C60 and C70 Fullerites in Air

被引：5
|
作者：
Aksenova, V. V. [1 ]
Nikonova, R. M. [1 ]
Lad'yanov, V. I. [1 ]
Tamm, N. B. [2 ]
Skokan, E. V. [2 ]
Pushkarev, B. E. [1 ]
机构：
[1] Russian Acad Sci, Physicotech Inst, Izhevsk 426000, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2013年 / 87卷 / 10期
关键词：
fullerites; oxidation; crystal solvates; IR spectroscopy; FULLERENE OXIDES; MOLECULAR-OXYGEN; TRANSFORMATION; OZONIDES; FILMS;
D O I：
10.1134/S0036024413090021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidation of C-60 and C-70 fullerites and C-60/C-70 mixture is accompanied by the decomposition of the carbon frameworks of the molecules at annealing temperatures of 250 and 445 degrees C. Fourier-IR and HPLC studies show that the oxidation/decomposition of C-70 molecules is more active than that of C-60. The stages of fullerite interaction with oxygen while heating in air were determined.
引用
收藏
页码：1749 / 1755
页数：7
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