Population splitting, trapping, and non-ergodicity in heterogeneous diffusion processes

被引:119
|
作者
Cherstvy, Andrey G. [1 ]
Metzler, Ralf [1 ,2 ]
机构
[1] Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
[2] Tampere Univ Technol, Dept Phys, FIN-33101 Tampere, Finland
基金
芬兰科学院;
关键词
SINGLE-PARTICLE TRACKING; ANOMALOUS DIFFUSION; LIVING CELLS; INTRACELLULAR-TRANSPORT; FRACTIONAL DYNAMICS; RANDOM-WALKS; INHOMOGENEOUS-MEDIA; LANGEVIN EQUATION; INFECTION PATHWAY; DISORDERED MEDIA;
D O I
10.1039/c3cp53056f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We consider diffusion processes with a spatially varying diffusivity giving rise to anomalous diffusion. Such heterogeneous diffusion processes are analysed for the cases of exponential, power-law, and logarithmic dependencies of the diffusion coefficient on the particle position. Combining analytical approaches with stochastic simulations, we show that the functional form of the space-dependent diffusion coefficient and the initial conditions of the diffusing particles are vital for their statistical and ergodic properties. In all three cases a weak ergodicity breaking between the time and ensemble averaged mean squared displacements is observed. We also demonstrate a population splitting of the time averaged traces into fast and slow diffusers for the case of exponential variation of the diffusivity as well as a particle trapping in the case of the logarithmic diffusivity. Our analysis is complemented by the quantitative study of the space coverage, the diffusive spreading of the probability density, as well as the survival probability.
引用
收藏
页码:20220 / 20235
页数:16
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