New bifunctional organocatalysts based on (R,R)-cyclohexane-1,2-diamine for the asymmetric addition of nucleophiles to aldehydes

被引：1
|
作者：
Maleev, V. I. [1 ]
Gugkaeva, Z. T. [1 ]
Tsaloev, A. T. [1 ]
Moskalenko, M. A. [1 ]
Khrustalev, V. N. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 01期
关键词：
organocatalysis; asymmetric synthesis; aldehydes; trimethylsilyl cyanide; diethylzinc; (R,R)-cyclohexane-1,2-diamine; DYNAMIC KINETIC RESOLUTION; TRIMETHYLSILYL CYANIDE; ORGANOZINC REAGENTS; DERIVATIVES; CATALYSIS; TADDOLS; ALDOL;
D O I：
10.1007/s11172-012-0008-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The amide and sulfamide derivatives of (1R,2R)-N,N-diethylcyclohexane-1,2-diamine can serve as organocatalysts for addition of Me3SiCN and Et2Zn to aldehydes.
引用
收藏
页码：51 / 58
页数：8
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