Reaction of a Stable Silylene with Tetrahydrofuran

被引：1

作者：

Gostevskii, B. A. ^{[1
]}

Albanov, A. I. ^{[1
]}

Igumenov, I. K. ^{[2
]}

Morozova, N. B. ^{[2
]}

Rakhlin, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2008年 / 78卷 / 10期

关键词：

Silylene; Triethylsilane; Phenylmethylsilicone; Triethylphosphine; Viscous Yellowish Liquid;

D O I：

10.1134/S107036320810023X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of 1,3-di-tert-butyl-2,2-dichloro-2,3-dihydro-1H-1,3,2-diazasilole with metallic potassium gave, instead of a stable silylene, 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2 lambda(2)-diazasilylolene, a product of insertion of the latter into the carbon-oxygen bond of tetrahydrofuran, 1,4-di-tert-butyl-6-oxa-1,4-diaza-5-silaspiro[4,5]dec-2-ene.

引用

页码：1952 / 1953

页数：2

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