Synthesis of Terphenyl Derivatives by Pd-Catalyzed Suzuki-Miyaura Reaction of Dibromobenzene Using 2N2O-Salen as a Ligand in Aqueous Solution

被引：6

作者：

Gu, Ningning ^{[1
]}

Liu, Yashuai ^{[1
]}

Liu, Ping ^{[1
]}

Ma, Xiaowei ^{[1
]}

Yan, Liu ^{[1
]}

Dai, Bin ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Xinjiang, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 10期

基金：

中国国家自然科学基金;

关键词：

terphenyls; synthesis; 2N2O-salen; palladium; catalyze; Suzuki-Miyaura reaction; CROSS-COUPLING REACTIONS; BIS(IMINO)PYRIDINE PALLADIUM(II) COMPLEXES; ONE-POT SYNTHESIS; FLUORINATED TERPHENYLS; SUBSTITUTED TERPHENYLS; CONVENIENT SYNTHESIS; EFFICIENT CATALYSTS; FUNCTIONALIZATION; SINGLE; GROWTH;

D O I：

10.1002/cjoc.201500446

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient catalytic system for Na2PdCl4 catalyzing the Suzuki-Miyaura reaction of dibromobenzene and arylboronic acid has been developed by using 2N2O-salen as a ligand in H2O/EtOH (V:V=4:1) at 100 degrees C. Using this method, the reactions of substrates containing sterically demanding ortho substituents (e.g. dibromobenzene and/or arylboronic acids) proceeded efficiently, with the corresponding terphenyl derivatives being produced in moderate to excellent yields. Furthermore, this method offers interesting features for the multi-gram scale synthesis of terphenyl compound.

引用

页码：1189 / 1193

页数：5

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