Atmospheric abundance of HULIS during wintertime in Indo-Gangetic Plain: impact of biomass burning emissions

This study reports for the first-time the ambient concentrations of HULIS mass (HULIS-OM, Humic-like substances) and HULIS-C (carbon) in PM10 (particulate matter with aerodynamic diameter10m) from the Indo-Gangetic Plain (IGP at Kanpur, wintertime). HULIS extraction followed by purification and isolation protocol with methanol: acetonitrile (1:1v/v) on HLB (Hydrophilic-Lipophilic Balanced) cartridge has been established. Quantification of HULIS-C was achieved on a total organic carbon (TOC) analyser whereas HULIS-OM was determined gravimetrically. Consistently high recovery (> 90%) of HULIS-C based on analysis of Humic standard (sodium salt of Humic acid) suggested suitability of our established analytical protocol involving solvent extraction, purification and accurate quantification of HULIS. HULIS-OM varied from 17.3-38gm(-3) during daytime and from 19.8-40.6gm(-3) during night in this study. During daytime the HULIS-OM constituted 20-30% mass fraction of OMTotal and 10-15% of PM10 mass. However, a relatively low contribution of HULIS-OM has been observed during the night. This observation has been attributed to higher concentrations of OM and PM10 in night owing to nighttime chemical reactivity and condensation of organics in conjunction with shallower planetary boundary layer height. Strong correlation of HULIS-C with K-BB(+) (R-2>0.80) and significant day-night variability of HULIS-C/WSOC ratio in conjunction with air-mass back trajectories (showing transport of pollutants from upwind IGP) suggest biomass burning emission and secondary transformations as important sources of HULIS over IGP. High-loading of atmospheric PM10 (as high as 440gm(-3)) with significant contribution of water-soluble organic aerosols (WSOC/OC: 0.40-0.80) during wintertime highlights their plausible potential role in fog and haze formation and their impact on regional-scale atmospheric radiative forcing over the IGP.