Comparative spectroscopic study of three ET-based charge-transfer salts

被引:0
|
作者
Yertsev, VM
Drozdova, OO
Semkin, VN
Vlasova, RM
Lyubovskaya, RN
机构
[1] Inst Venezolano Invest Cient, Ctr Fis, Caracas 1020A, Venezuela
[2] Russian Acad Sci, AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
[3] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Russia
关键词
infrared spectroscopy; organic conductors based on radical cation and or anion salts;
D O I
10.1016/S0379-6779(98)00932-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polarized reflectance spectra of kappa-phase ET2[Hg(SCN)Cl-2], ET2[Hg(SCN)(2)Br], and (D-8-ET)(2)[Hg(SCN)(2)Br] single crystals are measured in the range from 600 to 40000 cm(-1). The Hubbard model for orthogonal dimers is employed for interpretation of the observed charge-transfer bands and vibrational peaks resulting from electron-molecular vibration coupling.
引用
收藏
页码:2006 / 2007
页数:2
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