Environmentally Friendly Organic Synthesis Using Bismuth(III) Compounds

被引：10

作者：

Krabbe, Scott W. ^{[1
]}

Mohan, Ram S. ^{[1
]}

机构：

[1] Illinois Wesleyan Univ, Dept Chem, Lab Environm Friendly Organ Synth, Bloomington, IL 61701 USA

来源：

BISMUTH-MEDIATED ORGANIC REACTIONS | 2012年 / 311卷

关键词：

Acetals; Acylals; Allylations; Bismuth(III); 3,4-Dihydro-2H-1-benzopyrans; Ene reactions; Epoxide-olefin cyclizations; Piperidines; Tetrahydroquinolines; THP ethers; ONE-POT SYNTHESIS; HIGHLY EFFICIENT DEPROTECTION; TRIFLATE CATALYZED ALLYLATION; INTRAMOLECULAR ENE REACTIONS; DIELS-ALDER REACTION; CYCLIC ENOL ETHERS; SELECTIVE CONVERSION; DOMINO REACTION; STEREOSELECTIVE-SYNTHESIS; TETRAHYDROPYRANYL ETHERS;

D O I：

10.1007/128_2011_194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With increasing environmental concerns, the need for environmentally friendly organic synthesis has gained increased importance. In this regard, bismuth (III) compounds are especially attractive as "green" reagents and catalysts for organic synthesis. Bismuth(III) compounds are remarkably nontoxic, relatively air and moisture stable, and easy to handle. The contributions from our laboratory in the last 5 years in the field of applications of bismuth(III) compounds as catalysts are presented.

引用

页码：45 / 68

页数：24

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