Environmentally Friendly Organic Synthesis Using Bismuth(III) Compounds

被引:10
|
作者
Krabbe, Scott W. [1 ]
Mohan, Ram S. [1 ]
机构
[1] Illinois Wesleyan Univ, Dept Chem, Lab Environm Friendly Organ Synth, Bloomington, IL 61701 USA
来源
关键词
Acetals; Acylals; Allylations; Bismuth(III); 3,4-Dihydro-2H-1-benzopyrans; Ene reactions; Epoxide-olefin cyclizations; Piperidines; Tetrahydroquinolines; THP ethers; ONE-POT SYNTHESIS; HIGHLY EFFICIENT DEPROTECTION; TRIFLATE CATALYZED ALLYLATION; INTRAMOLECULAR ENE REACTIONS; DIELS-ALDER REACTION; CYCLIC ENOL ETHERS; SELECTIVE CONVERSION; DOMINO REACTION; STEREOSELECTIVE-SYNTHESIS; TETRAHYDROPYRANYL ETHERS;
D O I
10.1007/128_2011_194
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With increasing environmental concerns, the need for environmentally friendly organic synthesis has gained increased importance. In this regard, bismuth (III) compounds are especially attractive as "green" reagents and catalysts for organic synthesis. Bismuth(III) compounds are remarkably nontoxic, relatively air and moisture stable, and easy to handle. The contributions from our laboratory in the last 5 years in the field of applications of bismuth(III) compounds as catalysts are presented.
引用
收藏
页码:45 / 68
页数:24
相关论文
共 50 条
  • [1] Environmentally friendly organic synthesis using bismuth compounds: bismuth(III) iodide catalyzed deprotection of acetals in water
    Bailey, Aaron D.
    Baru, Ashvin R.
    Tasche, Kendall K.
    Mohan, Ram S.
    [J]. TETRAHEDRON LETTERS, 2008, 49 (04) : 691 - 694
  • [2] Environmentally friendly organic synthesis using bismuth compounds. Bismuth(III) bromide catalyzed synthesis of substituted tetrahydroquinoline derivatives
    Rogers, Jamie L.
    Ernat, Justin J.
    Yung, Herbie
    Mohan, Ram S.
    [J]. CATALYSIS COMMUNICATIONS, 2009, 10 (05) : 625 - 626
  • [3] Environmentally friendly organic synthesis using bismuth compounds. Bismuth trifluoromethanesulfonate-catalyzed allylation of dioxolanes
    Spafford, Matthew J.
    Christensen, James E.
    Huddle, Matthew G.
    Lacey, Joshua R.
    Mohan, Ram S.
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2008, 61 (06) : 419 - 421
  • [4] Applications of bismuth(III) compounds in organic synthesis
    Bothwell, Jason M.
    Krabbe, Scott W.
    Mohan, Ram S.
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (09) : 4649 - 4707
  • [5] Applications of bismuth(III) compounds in organic synthesis
    Leonard, NM
    Wieland, LC
    Mohan, RS
    [J]. TETRAHEDRON, 2002, 58 (42) : 8373 - 8397
  • [6] Synthesis of azo compounds using environmentally friendly route
    不详
    [J]. GOLD BULLETIN, 2009, 42 (01): : CGN1 - CGN1
  • [7] ORGANIC-SYNTHESIS USING BISMUTH AND BISMUTH COMPOUNDS
    WADA, M
    OHKI, H
    [J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1989, 47 (05) : 425 - 435
  • [8] A practical, cheap and environmentally friendly preparation of bismuth(III) trifluoromethanesulfonate
    Répichet, S
    Zwick, A
    Vendier, L
    Le Roux, C
    Dubac, J
    [J]. TETRAHEDRON LETTERS, 2002, 43 (06) : 993 - 995
  • [9] Bismuth(III) compounds as catalysts in organic synthesis: A mini review
    Lopez, Erick
    Thorp, Sophie C.
    Mohan, Ram S.
    [J]. POLYHEDRON, 2022, 222
  • [10] Bismuth Compounds in Organic Synthesis: Synthesis of Dioxanes, Dioxepines, and Dioxolanes Catalyzed by Bismuth(III) Triflate
    Podgorski, Daniel M.
    Krabbe, Scott W.
    Le, Long N.
    Sierszulski, Paul R.
    Mohan, Ram S.
    [J]. SYNTHESIS-STUTTGART, 2010, (16): : 2771 - 2775