Surfactant-assisted synthesis and electrochemical properties of an unprecedented polyoxometalate-based metal-organic nanocaged framework

被引:45
|
作者
Yang, Xiya [1 ,3 ]
Zhu, Peipei [1 ]
Ren, Jing [1 ]
Chen, Yuhao [1 ]
Li, Xiao [1 ]
Sha, Jingquan [1 ]
Jiang, Jianzhuang [2 ]
机构
[1] Jining Univ, Dept Chem & Chem Engn, Key Lab Inorgan Chem, Qufu 273155, Shandong, Peoples R China
[2] Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China
[3] Jiamusi Univ, Sch Pharm, Jiamusi 154007, Heilongjiang, Peoples R China
基金
中国博士后科学基金;
关键词
INTERCALATION; CLUSTER; DESIGN; PHASE;
D O I
10.1039/c8cc08559e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first polyoxometalate (POM)-containing nanocage based metal-organic framework (Zn-POMCF) was synthesized by a surfactant-assisted method. In contrast to the Zn-based metal-organic framework (Zn-MOF), the cooperative assembly of POM and a Zn/trz macrocycle gave rise to high stability and good electrochemical ability of the Zn-POMCF in lithium-ion batteries (LIBs).
引用
收藏
页码:1201 / 1204
页数:4
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