Effects of noble metal modification on surface oxygen composition, charge separation and photocatalytic activity of ZnO nanoparticles

In this paper, ZnO nanoparticles were modified by depositing different amount of noble metal Ag or Pd on their surfaces with a photoreduction method. The as-prepared ZnO samples were principally characterized by X-ray photoelectron spectroscopy (XPS) and surface photovoltage spectroscopy (SPS), and their activity was evaluated by a photocatalytic degradation reaction of phenol solution. The effects of noble metal modification on surface cornposition, photoinduced charge transfer behavior and photocatalytic activity of ZnO samples were mainly investigated. The results show that, after an appropriate amount of Ag or Pd is deposited on the ZnO surfaces, the O 1s XPS spectrum shifts to higher binding energy, indicating that the content of surface hydroxyl oxygen (O-H) increases. And the SPS intensity greatly decreases, indicating that the photoinduced electrons are easily captured by adsorbed oxygen via noble metal clusters so that the recombination of photoinduced electron and hole pairs is effectively inhibited. These are responsible for the enhancement in the photocatalytic activity. Moreover, the effects of Pd modification on photocatalytic activity is greater than that of Ag, which can be explained by means of surface hydroxyl content as well as charge separation situation. (c) 2005 Elsevier B.V. All rights reserved.