Recent studies on asymmetric hydrogenation. New catalysts and synthetic applications in organic synthesis

被引：21

作者：

Genet, JP ^{[1
]}

机构：

[1] Ecole Natl Super Chim Paris, Lab Synth Select Organ & Prod Nat, F-75231 Paris 05, France

来源：

PURE AND APPLIED CHEMISTRY | 2002年 / 74卷 / 01期

关键词：

D O I：

10.1351/pac200274010077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CODRu(eta(3)methylallyl)(2) is a versatile starting material for the preparation of a wide range of chiral bisphosphines ruthenium(II) complexes: (P*P)Ru(eta(3)methylallyl)(2) 2, Ru[X-4(P*P)(2)] 3, and cationic monohydride ruthenium complex 4. A facile synthesis of new C-2 electron-rich chiral phosphines, bis(phosphetano)benzene 8 and 1, 1' bis(phosphetano)ferrocene 10 is presented. Dynamic kinetic resolution was used for efficient syntheses of key components of the hexahydroazepane core 16 of balanol and of optically pure Boc-(2S,3R,3S)-iso-dolaproine 19. Catalyst 4 was used in asymmetric hydrogenation of 22 to give (+)-cis-methyl dihydrojasmonate in high enantioselectivity.

引用

页码：77 / 83

页数：7

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