Synthesis, Structure and Phase Transition of a New Microporous Aluminophosphate [C4N2H14]2+[H2Al3P3O14]2-

被引：11

作者：

Lu Hui-Ying ^{[1
]}

Tong Xiao-Qiang ^{[1
]}

Yan Yan ^{[1
]}

Yan Wen-Fu ^{[1
]}

Yu Ji-Hong ^{[1
]}

Xu Ru-Ren ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2013年 / 34卷 / 07期

关键词：

Molecular sieve; Aluminophosphate; Open framework; Hydrothermal synthesis; OPEN-FRAMEWORK ALUMINOPHOSPHATE; MOLECULAR-SIEVES; LAYERED ALUMINOPHOSPHATE; SIMULATION; CHANNELS; CHAIN; ZN; CO;

D O I：

10.7503/cjcu20130245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of N-methyl-1,3-diaminopropane, a new microporous aluminophosphate compound [C4N2H14](2+)[H2Al3P3O14](2-)(1) was synthesized under hydrothermal condition. Single-crystal X-ray diffraction structural analysis showed that compound 1 crystallizes in the orthorhombic space group Pbca with a = 1.59839 ( 11) nm, b=0.99402 (6) nm, c=1.82261(11) nm, V=2.8958(3) nm(3). Its framework consists of AlO5/AlO6 and PO4 units forming 10-ring channels along [010] direction, where the templates exists. Compound 1 transformed to AlPO4-25(ATV) upon calcination at 550 degrees C. It was further characterized by powder X-ray diffraction (PXRD), inductively coupled plasma (ICP) analysis, scanning electron microscopy (SEM), thermal gravimetric(TG) analysis, and elemental analysis.

引用

页码：1571 / 1575

页数：5

共 28 条

[11] |(C4NH12)4|[M4Al12P16O64] (M = Co, Zn): New Heteroatom-Containing Aluminophosphate Molecular Sieves with Two Intersecting 8-Ring Channels
Liu, Zhuo
Song, Xiaowei
Li, Jiyang
Li, Yi
Yu, Jihong
Xu, Ruren
[J]. INORGANIC CHEMISTRY, 2012, 51 (03) : 1969 - 1974
[12] Synthesis and structure of a three-dimensional open-framework aluminophosphate [NH2(CH2)(3)NH3](+)[HAl3P3O14](-)center dot H2O, containing AlO5 and AlO6 polyhedra
Natarajan, S
Gabriel, JCP
Cheetham, AK
[J]. CHEMICAL COMMUNICATIONS, 1996, (12) : 1415 - 1416
[13] Aluminophosphate chain-to-layer transformation
Oliver, S
Kuperman, A
Lough, A
Ozin, GA
[J]. CHEMISTRY OF MATERIALS, 1996, 8 (09) : 2391 - 2398
[14] Heteroatom-Stabilized Chiral Framework of Aluminophosphate Molecular Sieves
Song, Xiaowei
Li, Yi
Gan, Lin
Wang, Zhuopeng
Yu, Jihong
Xu, Ruren
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (02) : 314 - 317
[15] Sun XY, 2011, CHEM RES CHINESE U, V27, P318
[16] Tian T, 2011, CHEM J CHINESE U, V32, P577
[17] Synthesis, crystal structure and characterization of AP2DAO, a new layered aluminophosphate templated by 1,8-diaminooctane molecules
Tuel, A
Gramlich, V
Baerlocher, C
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 47 (2-3) : 217 - 229
[18] LEV-zeotype magnesium aluminophosphates with variable Mg/Al ratios
Wang, Yanyan
Shao, Lang
Li, Yi
Li, Xu
Li, Jiyang
Yu, Jihong
Xu, Ruren
[J]. DALTON TRANSACTIONS, 2012, 41 (22) : 6855 - 6860
[19] ALUMINOPHOSPHATE MOLECULAR-SIEVES - A NEW CLASS OF MICROPOROUS CRYSTALLINE INORGANIC SOLIDS
WILSON, ST
LOK, BM
MESSINA, CA
CANNAN, TR
FLANIGEN, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (04) : 1146 - 1147
[20] Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7
Xing, Hongzhu
Li, Jiyang
Yan, Wenfu
Chen, Peng
Jin, Zhao
Yu, Jihong
Dai, Sheng
Xu, Ruren
[J]. CHEMISTRY OF MATERIALS, 2008, 20 (13) : 4179 - 4181

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