Bimetallic Metal Organic Frameworks as Magnetically Separable Heterogeneous Catalysts and Photocatalytic Dye Degradation

被引：16
|
作者：
Tiwari, Ashish [1 ]
Sagara, Prateep Singh [2 ]
Varma, Vicky [2 ]
Randhawa, Jaspreet Kaur [1 ]
机构：
[1] Indian Inst Technol Mandi, Sch Engn, Mandi 175005, Himachal Prades, India
[2] Indian Inst Technol Mandi, Sch Basic Sci, Mandi 175005, Himachal Prades, India
来源：
CHEMPLUSCHEM | 2019年 / 84卷 / 01期
关键词：
bis(indolyl)methanes; dye degradation; metal-organic frameworks; photocatalysis; EFFICIENT; MOFS; PERFORMANCE; ADSORPTION; STABILITY; MN;
D O I：
10.1002/cplu.201800546
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new bimetallic MOF (BMOF) has been synthesized using iron and zinc as inorganic metal nodes and 1,4-benzenedicarboxylic acid (BDC) as the organic linker molecule. BMOF was confirmed by single-crystal X-ray diffraction (SCXRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy high-angle annular dark-field imaging (TEM-HAADF), field emission scanning electron microscopy energy-dispersive X-ray analysis (FESEM-EDX), vibrating sample magnetometry (VSM) and inductively coupled plasma mass spectrometry (ICP-MS) analysis. The synthesized BMOF shows excellent optical and magnetic properties. BMOF acts as a heterogeneous catalyst and shows high catalytic activity towards bis(indolyl)methane synthesis and photocatalytic degradation of methylene blue (MB) under visible-light illumination.
引用
下载
收藏
页码：136 / 141
页数：6
相关论文
共 50 条
  • [31] A Review on Metal-Organic Frameworks as Congenial Heterogeneous Catalysts for Potential Organic Transformations
    Gangu, Kranthi Kumar
    Jonnalagadda, Sreekantha B.
    FRONTIERS IN CHEMISTRY, 2021, 9
  • [32] Metal-organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations
    Chughtai, Adeel H.
    Ahmad, Nazir
    Younus, Hussein A.
    Laypkov, A.
    Verpoort, Francis
    CHEMICAL SOCIETY REVIEWS, 2015, 44 (19) : 6804 - 6849
  • [33] Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts
    Dhakshinamoorthy, Amarajothi
    Asiri, Abdullah M.
    Garcia, Hermenegildo
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (14) : 5238 - 5261
  • [34] Strategic combination of metal–organic frameworks and C3N4 for expeditious photocatalytic degradation of dye pollutants
    Ome Parkash Kumar
    Muhammad Ahmad
    Muhammad Altaf Nazir
    Aqsa Anum
    Muhammad Jamshaid
    Syed Shoaib Ahmad Shah
    Aziz Rehman
    Environmental Science and Pollution Research, 2022, 29 : 35300 - 35313
  • [35] Magnetically separable carbon capsules loaded with laccase and their application to dye degradation
    Valle-Vigon, Patricia
    Fuertes, Antonio B.
    RSC ADVANCES, 2011, 1 (09): : 1756 - 1762
  • [36] Structure and photocatalytic performance of magnetically separable titania photocatalysts for the degradation of propachlor
    Belessi, V.
    Lambropoulou, D.
    Konstantinou, I.
    Zboril, R.
    Tucek, J.
    Jancik, D.
    Albanis, T.
    Petridis, D.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 87 (3-4) : 181 - 189
  • [37] Activation of Peroxymonosulfate by Co-Metal-Organic Frameworks as Catalysts for Degradation of Organic Pollutants
    Mao, Wenjia
    Wang, Xinting
    Hu, Xiaoli
    Lin, Zihan
    Su, Zhongmin
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (36) : 13223 - 13232
  • [38] Enhanced Heterogeneous Fenton Degradation of Organic Dyes by Bimetallic Zirconia-Based Catalysts
    Aneggi, Eleonora
    Hussain, Sajid
    Baratta, Walter
    Zuccaccia, Daniele
    Goi, Daniele
    MOLECULES, 2024, 29 (09):
  • [39] Merging molecular catalysts and metal-organic frameworks for photocatalytic fuel production
    Stanley, P. M.
    Haimerl, J.
    Shustova, N. B.
    Fischer, R. A.
    Warnan, J.
    NATURE CHEMISTRY, 2022, 14 (12) : 1342 - 1356
  • [40] Contribution of metal species to the heterogeneous photocatalytic degradation of natural organic matter
    Uyguner, Ceyda Senem
    Bekbolet, Miray
    INTERNATIONAL JOURNAL OF PHOTOENERGY, 2007, 2007
12345