Nickel-catalyzed C(sp2)-C(sp2) Cross Coupling Reactions of Sulfur-Functionalities and Grignard Reagents

被引：42
|
作者：
Someya, Chika I. [1 ]
Weidauer, Maik [1 ]
Enthaler, Stephan [1 ]
机构：
[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany
来源：
CATALYSIS LETTERS | 2013年 / 143卷 / 05期
关键词：
Catalysis; Cross coupling; Nickel; Sulfur compounds; Grignard reagents; BOND-FORMING REACTIONS; STEREOSELECTIVE-SYNTHESIS; ALKENYL SULFOXIMINES; THIOL ESTERS; SELECTIVE FUNCTIONALIZATION; DIORGANOZINC REAGENTS; UNSYMMETRICAL BIARYLS; ORGANOZINC REAGENTS; TRANSITION-METALS; EXCHANGE-REACTION;
D O I：
10.1007/s10562-013-0979-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present study, the nickel-catalyzed carbon carbon bond formation of a range of sulfur containing substrates with Grignard reagents via desulfurization has been explored. After investigation of different reaction parameters with a well-defined nickel complex an excellent and easy-accessible pre-catalyst was found. The obtained system was capable to convert a broad scope of substrates under mild reaction conditions.
引用
收藏
页码：424 / 431
页数：8
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