Stereoselective synthesis of conjugated all-trans-tetraenes. Application to the synthesis of beta-parinaric acid methyl ester.

被引：10
|
作者：
Solladie, G
Kalai, C
Adamy, M
Colobert, F
机构：
[1] Lab. de Stereochim. Associe au CNRS, ECPM, Université Louis Pasteur, 67008-Strasbourg
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 39期
关键词：
D O I：
10.1016/S0040-4039(97)01594-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
in this paper is reported the stereoselective synthesis of all-trans-tetraenes by reductive elimination of 1,8-dibenzoate-2,4,6-trienes with sodium amalgam. The method was applied to the syntheses of 4E, 6E, 8E, 10E-heptatetraene and beta-parinaric acid methyl ester. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：6917 / 6920
页数：4
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