Synthesis and chemical properties of polyacetylenic derivatives of benzo- and dibenzo-crown ethers

被引：7
|
作者：
Klyatskaya, SV [1 ]
Tretyakov, EV [1 ]
Vasilevsky, SF [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia
来源：
ARKIVOC | 2003年
关键词：
benzocrown ethers; alkynes; cross-coupling reaction; polyethynylbenzocrown ethers; aminoalkylation; the retro-Favorsky reaction; the Mannich reaction; homogeneous catalysis;
D O I：
10.3998/ark.5550190.0004.d04
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
4',5'-Diethynylbenzo-15-crown-5-(6), 4', 5'(5")-diethynyldibenzo-18-crown-6(10, 11) and 4',5',4",5"'-tetraethynyl-dibenzo-18-crown-6(12) ethers were synthesized by cross-coupling of the corresponding di- and tetra-iodides (1-4) with trimethylsilylacetylene (5a) or 2-methylbut-3-yn-2-ol(5c) followed by treatment of the resulting products with alkali. The Mannich reaction with the di- and tetraethynyl derivatives was also carried out.
引用
收藏
页码：21 / 34
页数：14
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