Highly selective and efficient conversion of alkyl aryl and alkyl cyclopropyl ketones to aromatic and cyclopropane carboxylic acids by aerobic catalytic oxidation: A free-radical redox chain mechanism.

被引：0

作者：

Minisci, F

Recupero, F

Fontana, F

Bjorsvik, HR

Liguori, L

机构：

[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim G Natta, I-20131 Milan, Italy

[2] Univ Bergamo, Dipartimento Ingn, I-24044 Milan, Italy

[3] Univ Bergen, Dept Chem, N-5007 Bergen, Norway

来源：

SYNLETT | 2002年 / 04期

关键词：

carboxylic acids; kjetones; oxidation by molecular oxygen; free-radical; redox catalysis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and convenient method has been developed for the oxidation of aryl alkyl and cyclopropyl alkyl ketones to aromatic and cyclopropane carboxylic acids by molecular oxygen at atmospheric pressure, catalysed by Mn(NO3)(2) in combination with Co(NO3)(2) or Cu(NO3)(2). This simple, cheap and highly selective process has a general character for the synthesis of carboxylic acids and it is particularly suitable for industrial applications.

引用

页码：610 / 612

页数：3