Photochemical and Photoelectrochemical Reduction of CO2

被引：894

作者：

Kumar, Bhupendra ^{[1
]}

Llorente, Mark ^{[1
]}

Froehlich, Jesse ^{[2
]}

Dang, Tram ^{[1
]}

Sathrum, Aaron ^{[1
]}

Kubiak, Clifford P. ^{[1
,2
]}

机构：

[1] Univ Calif San Diego, Mat Sci & Engn Program, La Jolla, CA 92093 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 63 | 2012年 / 63卷

关键词：

solar fuels; molecular catalyst; photocathode; semiconductor/catalyst junction; homogeneous catalysis; heterogeneous catalysis; P-TYPE SILICON; INDIUM-PHOSPHIDE ELECTRODES; AQUEOUS CARBON-DIOXIDE; PARA-GALLIUM ARSENIDE; HIGH-PRESSURE CO2; ELECTROCHEMICAL REDUCTION; ELECTROCATALYTIC REDUCTION; SEMICONDUCTOR-LIQUID; PHOTOELECTROCATALYTIC REDUCTION; CATALYZED PHOTOREDUCTION;

D O I：

10.1146/annurev-physchem-032511-143759

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recent literature on photochemical and photoelectrochemical reductions of CO2 is reviewed. The different methods of achieving light absorption, electron-hole separation, and electrochemical reduction of CO2 are considered. Energy gap matching for reduction of CO2 to different products, including CO, formic acid, and methanol, is used to identify the most promising systems. Different approaches to lowering overpotentials and achieving high chemical selectivities by employing catalysts are described and compared.

引用

页码：541 / +

页数：54

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