Performance enhancement of biodiesel fueled SOFC using paper-structured catalyst

被引：19
|
作者：
Shiratori, Yusuke [1 ,2 ,3 ]
Tran Quang-Tuyen [1 ]
Sasaki, Kazunari [1 ,2 ,3 ,4 ]
机构：
[1] Kyushu Univ, Fac Engn, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI, Nishi Ku, Fukuoka 8190395, Japan
[3] Kyushu Univ, Next Generat Fuel Cell Res Ctr, Nishi Ku, Fukuoka 8190395, Japan
[4] Kyushu Univ, Int Res Ctr Hydrogen Energy, Nishi Ku, Fukuoka 8190395, Japan
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 23期
关键词：
Solid oxide fuel cell; Biodiesel; Oleic-FAME; Paper-structured catalyst; CARBON DEPOSITION; DIRECT OXIDATION; ANODE MATERIALS; ACID; CELL; FEASIBILITY; BEHAVIOR; PFAD;
D O I：
10.1016/j.ijhydene.2013.05.128
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, performance of solid oxide fuel cell (SOFC) connected with paper-structured catalyst (PSC) was evaluated in the direct feed of wet oleic fatty acid methyl ester (oleic-FAME, C19H36O2), which is a mono-unsaturated component of practical biodiesel fuels (BDFs), in the steam to carbon ratio (S/C) range between 2.0 and 3.5, and high current density of 1 A cm(-2) (at 0.7 V) was recorded at 800 degrees C. Long term stability of oleic-FAME fueled SOFC was achieved by the incorporation of PSC into SOFC even under severe operating condition prone to coking (direct feed of unsaturated hydrocarbon with carbon number 19 and low S/C ratio of 2.0). After 100 h test, coking was not observed in both SOFC anode and PSC. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：9856 / 9866
页数：11
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