Current density distribution;
Pore network modelling;
Condensation;
Gas diffusion layer;
Rib-channel;
Continuum - PNM coupled model;
GAS-DIFFUSION LAYERS;
PORE-NETWORK;
LIQUID WATER;
2-PHASE FLOW;
TRANSPORT PHENOMENA;
COUPLED CONTINUUM;
CATHODE;
MODEL;
PEFCS;
DURABILITY;
D O I:
10.1016/j.ijhydene.2018.01.097
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Experimental results based on in-situ measurements at the interface between the catalyst layer and the gas diffusion layer (GDL) on the cathode side at the channel - rib scale show an interesting variation of the current density distribution as the mean current density is increased. It is found that the local current density below the rib median axis corresponds to a maximum at low to intermediate mean current densities and to a minimum when the mean current density is sufficiently high. Also, the higher is the current density, the more marked the minimum. From numerical simulations, it is shown that the current density distribution inversion phenomenon is strongly correlated to the liquid water zone development within the GDL. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机构:
Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Energy Technol Area, Berkeley, CA 94720 USAUniv Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
Ehlinger, Victoria M.
Kusoglu, Ahmet
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机构:
Lawrence Berkeley Natl Lab, Energy Technol Area, Berkeley, CA 94720 USAUniv Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
Kusoglu, Ahmet
Weber, Adam Z.
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机构:
Lawrence Berkeley Natl Lab, Energy Technol Area, Berkeley, CA 94720 USAUniv Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA