Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)

被引：0

作者：

Pintauer, Tomislav ^{[1
]}

机构：

[1] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA

来源：

CONTROLLED RADICAL POLYMERIZATION, VOL 1: MECHANISMS | 2015年 / 1187卷

基金：

美国国家科学基金会;

关键词：

ALKYNE 3+2 CYCLOADDITION; ELECTRON-TRANSFER; MECHANISTIC ASPECTS; RATE CONSTANTS; COMPLEXES; COORDINATION; OXYGENATION; ACTIVATION; REACTIVITY; EFFICIENT;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copper complexes with tris(2-pyridylmethyl)amine (TPMA) ligand are currently among the most active catalysts in atom transfer radical addition (ATRA) and polymerization (ATRP) reactions that utilize reducing agents. Both processes originated from well-known Kharasch addition in which polyhalogenated compounds were added to alkenes via free-radical means. The main focus of this article is to review structural and mechanistic aspects of ATRA and ATRP reactions catalyzed by copper complexes with TPMA ligand. Special emphasis will be placed on recently developed substituted TPMA based ligands that contain electron donating groups.

引用

页码：105 / 128

页数：24

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