Halogenation of N-substituted p-quinone imines and p-quinone oxime esters:: IV.: Chlorination and bromination of N-arylsulfonyl-2(3)-methyl(2-chloro)-1,4-benzoquinone monoimines

被引：12

作者：

Avdeenko, AP ^{[1
]}

Konovalova, SA ^{[1
]}

机构：

[1] Donbass State Machine Bldg Acad, UA-84313 Kramatorsk, Ukraine

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 42卷 / 03期

关键词：

D O I：

10.1134/S1070428006030031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of halogens to N-arylsulfonyl-1,4-benzoquinone imines, which exist in a solution as Z and E isomers, is controlled by the steric factor. Z-E Isomerization strongly affects the stability of cyclohexene structures formed by halogenation of 1,4-benzoquinone imines. The halogenation of N-arylsulfonyl-1,4-benzoquinone imines was found to be accompanied by prototropic rearrangement.

引用

页码：349 / 364

页数：16