Ligand-free C-N bond formation in aqueous medium using a reusable Cu-Mn bimetallic catalyst

被引：21

作者：

Sawant, Sanghapal D. ^{[1
,2
]}

Srinivas, Mahesuni ^{[1
,2
]}

Kumar, K. A. Aravinda ^{[1
]}

Reddy, G. Lakshma ^{[1
,2
]}

Singh, Parvinder Pal ^{[1
,2
]}

Singh, Baldev ^{[2
,3
]}

Sharma, Amit Kumar ^{[5
]}

Sharma, P. R. ^{[4
]}

Vishwakarma, Ram A. ^{[1
,2
]}

机构：

[1] CSIR Indian Inst Integrat Med, Div Med Chem, Jammu 180001, India

[2] Acad Sci & Innovat Res, New Delhi 110001, India

[3] CSIR Indian Inst Integrat Med, Jammu 180001, India

[4] CSIR Indian Inst Integrat Med, Canc Pharmacol Div, Jammu 180001, India

[5] Univ Jammu, Dept Chem, Jammu 180006, India

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 39期

关键词：

N-Arylamine; C-N bond; Cu-Mn bimetallic catalyst; CROSS-COUPLING REACTIONS; ARYL HALIDES; ARYLBORONIC ACIDS; ALIPHATIC-AMINES; ARYLATION; PHENOLS; ETHERS;

D O I：

10.1016/j.tetlet.2013.07.095

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general ligand-free protocol has been described for the recyclable and reusable Cu-Mn catalyzed C-N bond forming cross coupling reaction of arylboronic acids with various amines to form N-arylated amine products in aqueous medium affording excellent yields under ambient conditions, in 3-4 h. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：5351 / 5354

页数：4

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