Ligand-free C-N bond formation in aqueous medium using a reusable Cu-Mn bimetallic catalyst

被引:21
|
作者
Sawant, Sanghapal D. [1 ,2 ]
Srinivas, Mahesuni [1 ,2 ]
Kumar, K. A. Aravinda [1 ]
Reddy, G. Lakshma [1 ,2 ]
Singh, Parvinder Pal [1 ,2 ]
Singh, Baldev [2 ,3 ]
Sharma, Amit Kumar [5 ]
Sharma, P. R. [4 ]
Vishwakarma, Ram A. [1 ,2 ]
机构
[1] CSIR Indian Inst Integrat Med, Div Med Chem, Jammu 180001, India
[2] Acad Sci & Innovat Res, New Delhi 110001, India
[3] CSIR Indian Inst Integrat Med, Jammu 180001, India
[4] CSIR Indian Inst Integrat Med, Canc Pharmacol Div, Jammu 180001, India
[5] Univ Jammu, Dept Chem, Jammu 180006, India
关键词
N-Arylamine; C-N bond; Cu-Mn bimetallic catalyst; CROSS-COUPLING REACTIONS; ARYL HALIDES; ARYLBORONIC ACIDS; ALIPHATIC-AMINES; ARYLATION; PHENOLS; ETHERS;
D O I
10.1016/j.tetlet.2013.07.095
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A general ligand-free protocol has been described for the recyclable and reusable Cu-Mn catalyzed C-N bond forming cross coupling reaction of arylboronic acids with various amines to form N-arylated amine products in aqueous medium affording excellent yields under ambient conditions, in 3-4 h. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5351 / 5354
页数:4
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