Electrical response of ammonium-rich water ice

The electrical properties of water ice impact the study of diverse frozen environments, in particular the radar sounding of ice masses. The high-frequency response of meteoric polar ice depends partly on the bulk concentration of ammonium (NH4+), but the nature of this response has been unclear. Here we use broadband dielectric spectroscopy to investigate the electrical response of laboratory-frozen solutions. By analyzing the relaxation frequency of these samples and its temperature dependence, we show that the mobility of Bjerrum D-defects formed in the ice lattice by ammonium is 1.4 +/- 0.8 x 10(-9) m(2) V-1 s(-1) at -20 degrees C, or about an order of magnitude smaller than that of Bjerrum L-defects formed by chloride. However, co-substitution of both ions increases the ice-lattice solubility of chloride by a factor of similar to 7, causing an enhanced conductivity response due to greater concentrations of Bjerrum L-defects. Thus, despite its low mobility, ammonium can also affect the high-frequency electrical response of polar ice, but its covariance with chloride must be considered.