Catalytic oxidation of aqueous sulfide in the presence of ferrites (MFe2O4, M = Fe, Cu, Co)

被引：32
|
作者：
Cunha, Igor T. [1 ]
Teixeira, Ivo F. [2 ]
Albuquerque, Adriana S. [3 ]
Ardisson, Jose D. [3 ]
Macedo, Waldemar A. A. [3 ]
Oliveira, Henrique S. [1 ]
Tristao, Juliana C. [4 ]
Sapag, Karim [5 ]
Lago, Rochel M. [1 ]
机构：
[1] Chem Dept UFMG, Belo Horizonte, MG, Brazil
[2] Univ Oxford, Dept Chem, Oxford OX1 3QZ, England
[3] CDTN, Appl Phys Lab, Belo Horizonte, MG, Brazil
[4] Chem Dept UFV, Florestal, MG, Brazil
[5] Univ Nacl San Luis, Dept Phys, San Luis, Argentina
来源：
CATALYSIS TODAY | 2016年 / 259卷
关键词：
Ferrite; Sulfide oxidation; Polysulfide; HYDROGEN-SULFIDE; ACTIVATED CARBON; IRON; H2S; COBALT; NANOCOMPOSITES; ADSORPTION; PRODUCTS; COPPER; OXYGEN;
D O I：
10.1016/j.cattod.2015.07.023
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In this work, the spinel structured iron oxides, MFe2O4 (M= Cu2+ and Co2+), magnetite (Fe3O4) and maghemite (gamma-Fe2O3) were investigated as catalyst for the sulfide oxidation in aqueous medium. XRD, Mossbauer, BET, TPR, SEM/EDS and XPS analyses suggest the formation of the spinel phase with surface areas varying from 75 to 105 m(2) g(-1) and the metal ions Cu2+ and Co2+ located in the octahedral and tetrahedral sites. It was observed that the presence of Co and especially Cu strongly increased the catalytic activity for the oxidation of sulfide to polysulfides, i.e. S-x(2-) (x= 1-4) and other S-O species. The strong effect of Cu2+ is discussed in terms of thermodynamically favorable processes comprising a strong surface interaction of S2--Cu2+, an electron transfer from sulfide to produce Cu1+ followed by an electron transfer from Cu1+ to Fe (3+)(bulk). (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：222 / 227
页数：6
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