Crystal structure of tylophorine methiodide monohydrate, C25H30NO4+I-center dot H2O

被引：2
|
作者：
Mitra, SN
Rajan, SS
Govindachari, TR
Subramanian, E
机构：
[1] UNIV MADRAS,DEPT CRYSTALLOG & BIOPHYS,MADRAS 600025,TAMIL NADU,INDIA
[2] SPIC FDN,DIV CHEM RES,MADRAS 600025,TAMIL NADU,INDIA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 03期
关键词：
tylophorine; anti-asthmatic drug;
D O I：
10.1007/BF01673675
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of tylophorine (Chemical name 2,3,6,7 tetramethoxy phenanthro [9,10:6',7'] indolizidine. Contribution No. 0871.) methiodide monohydrate has been determined. C25H30NO4+I- . H2O, triclinic, P (1) over bar, a = 8.831(1)Angstrom, b = 10.842(2), c = 13.902(2), alpha = 105.9(1)degrees, beta = 104.7(1), gamma = 97.3(1), V = 1210.22 Angstrom(3), Z = 2, D-x = 1.428 g/cm(-3), lambda(CuK alpha) = 1.54184 Angstrom, mu(CuK alpha) = 107.2 cm(-1), F(000) = 544, T = 295 degrees K, R = 0.038, Rw = 0.046, for 2331 observed reflections with I greater than or equal to 2 sigma(I). Apart from van der Waals forces, the structure is stabilized by two hydrogen bonds of the type Ow(H)...O and Ow(H)...I- involving the water molecule as the donor and atom O4 of the methoxy group and I- as accepters.
引用
收藏
页码：223 / 226
页数：4
相关论文
共 50 条
  • [21] Crystal structure of iminodiacetic acid monomethyl ester monohydrate, C5H9NO4 • H2O
    Silva, MR
    Beja, AM
    Paixao, JA
    Sobral, AJFN
    Cabral, LML
    Lopes, SH
    Gonsalves, AMD
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (04): : 535 - 536
  • [22] CRYSTAL STRUCTURE OF {[La-2(CNCH2COO)(6)(H2O)(4)]center dot H2O}(n) COMPLEX
    Lazarescu, Ana
    Melnic, Elena
    Shova, Sergiu
    Kravtsov, Victor
    Turta, Constantin
    CHEMISTRY JOURNAL OF MOLDOVA, 2015, 10 (01): : 52 - 56
  • [23] Crystal structure of tetraaqua gadolinium trinitrate monohydrate, [Gd(NO3)3(H2O)4] • H2O
    Stockhause, S
    Meyer, G
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (03): : 315 - 315
  • [24] Crystal structure of hexaaquanickel(II) hydrogenphosphate monohydrate, [Ni(H2O)6][HPO4] • H2O
    Wang, XW
    Wang, P
    Zheng, YQ
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2005, 220 (03): : 321 - 322
  • [25] Triperchloratoytterbium(III) monohydrate, Yb(ClO4)(3)center dot H2O
    Belin, C
    Favier, F
    Pascal, JL
    TillardCharbonnel, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 1872 - 1874
  • [26] Crystal structure of lithium potassium tartrate monohydrate, LiKC4H4O6•H2O
    Ottenz, C
    Schürmann, M
    Preut, H
    Bleckmann, P
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (01): : 166 - 166
  • [27] Crystal structure of N-butylammonium phthalate monohydrate, 2(C4H12N)+(C8H4O4)2-•H2O, C16H30N2O5
    Li, Jian
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (03): : 327 - 328
  • [28] Crystal structure of caffeinium perchlorate monohydrate, (C8H11N4O2)[ClO4] • H2O
    Wang, W. -D.
    Wang, H.
    Feng, W. -J.
    Jin, Z. -M.
    Hu, M. -L.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2006, 221 (03): : 375 - 376
  • [29] Crystal structure of Ba[Sn(Edta)(OH)]Cl-4 center dot H2O
    Poznyak, AL
    Ilyukhin, AB
    CRYSTALLOGRAPHY REPORTS, 1997, 42 (05) : 861 - 862
  • [30] Crystal structure of manganese(II) biquinolinedicarboxylate monohydrate, Mn(H2O)(C20H10N2O4)
    Karthikeyan, Sangeetha
    Irrgang, Torsten
    Kempe, Rhett
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (01): : 53 - 54
12345