Highly efficient photochemical HCOOH production from CO2 and water using an inorganic system

We have constructed a system that uses solar energy to react CO2 with water to generate formic acid (HCOOH) at an energy conversion efficiency of 0.15%. It consists of an AlGaN/GaN anode photoelectrode and indium (In) cathode that are electrically connected outside of the reactor cell. High energy conversion efficiency is realized due to a high quantum efficiency of 28% at 300 nm, attributable to efficient electron-hole separation in the semiconductor's heterostructure. The efficiency is close to that of natural photosynthesis in plants, and what is more, the reaction product (HCOOH) can be used as a renewable energy source. Copyright 2012 Author(s). This article is distributed under a Creative Commons Attribution 3.0 Unported License. [http://dx.doi.org/10.1063/1.4769356]