Alkaline activation of the donbass coals of different ranks

被引:5
|
作者
Tamarkina, Yu. V. [1 ]
Kucherenko, V. A. [1 ]
Shendrik, T. G. [1 ]
机构
[1] Natl Acad Sci Ukraine, Litvinenko Inst Phys Organ Chem & Coal Chem, Donetsk, Ukraine
关键词
CHEMICAL ACTIVATION; KOH ACTIVATION; BROWN-COAL; CARBONS; ADSORPTION; CAPACITANCE; MECHANISM;
D O I
10.3103/S0361521913010096
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The effect of the rank of coal (C (daf) = 80-95.2%) on the yield and characteristics of activated carbons prepared under the conditions of alkaline activation (800A degrees C, 1 h, Ar) at KOH/coal ratios of 1 g/g was studied. Under these conditions, the ability of coals to form porous materials decreased in the metamorphic series. Grade D coal (C (daf) = 80%) exhibited a maximum activation ability to form a material with S (BET) = 1560 m(2)/g, V (I ) pound = 0.71 cm(3)/g, and V (mi) = 0.51 cm(3)/g. A minimum activation ability was found in anthracite (C (daf) = 95.2%), which forms activated carbon with poorly developed porosity (S (BET) = 306 m(2)/g, V (I ) pound = 0.15 cm(3)/g, and V (mi) = 0.11 cm(3)/g).
引用
收藏
页码:1 / 6
页数:6
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