Synthesis, Crystal Structure and Fluorescent Properties of Silver and Cadmium Complexes(1)

被引：0
|
作者：
Wang Qing-Wei [1 ]
Liu Bo [1 ]
Sui Wei [1 ]
机构：
[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Dept Chem, Siping 136000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 03期
关键词：
hydrothermal synthesis; crystal structure; Ag(I) complex; Cd(II) complex; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMER; THEORETICAL CALCULATIONS; BIS(IMIDAZOL) LIGANDS; ACID; MOLECULES;
D O I：
10.14102/j.cnki.0254-5861.2011-1758
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new complexes [Ag(bix)](n)center dot nNAA center dot nH(2)O (1) and [Cd(NAA)(phen)(2)(H2O)](2)center dot 2CH(3)COO-center dot H2O (2) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene, HNAA = alpha-naphthylacetic acid, phen = 1,10-phenanthroline) have been successfully synthesized under hydrothermal conditions. Their structures have been determined by elemental analyses, IR spectroscopy, TG and single-crystal X-ray diffraction analysis. The intermolecular hydrogen bonding or pi-pi stacking interactions extend the complexes into a 3D supramolecular structure. Moreover, the luminescent properties of complex 2 have been investigated in the solid state.
引用
收藏
页码：453 / 460
页数：8
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